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Hold CTRL as the game is starting up, it'll take longer to load but that's because it's compiling.
You can also go into debug > Other options > Compile data.
What version of Essentials are you using?
And as mentioned above, post updates to a single thread.
This is especially helpful so that all details are in one place for us to see.
I've tried holding CTRL as it's booting up and the same problem still occurs, so could you please tell me where this debug option is? I think you're referring to the debug mode in RPG Maker but I'm not sure. I'm using Pokémon Essentials v19.1.
v19.1 will compile data whenever you change a PBS file so usually compiling is not required on your end.
Either way, go into the game and click F9 to open debug, try compiling the game from there.
Please provide a screenshot of the PBS file to confirm that everything is okay there.