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Well, if you look here and then you look here, can you find any moves that Roselia can learn before it evolves into Roserade that it can't learn when it evolves, and vice versa?
Courtesy of serebii once again, choice specs roserade:
Roserade@Specs
Timid
252SpAtt/252Spd/6HP
Leaf Storm
Sludge Bomb
HP Fire
Extrasensory
So you really need to breed for the best movesets. Especially on a poke like roserade, which isnt too flexible in the way of movesets
I evovled my Roselia at level forty, for the move Petal Dance. The best time though would be at level 46, because you get all of Roselia's strong moves, and because Roserade won't learn any good moves.