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I agree, I had used 10 ultra, 5 timer, a Premier ball(for lols) and then tried my only Dusk I had, before just saying forget it and using masterball ^^
I used my Masterball in Platinum. Seriously, though. Giratina was being very difficult. I went through three! Three sessions! of using 70+ Ultra/Dusk balls with it having like four HP left. And It wouldn't let me catch it! >.<
Like all Pokemon that appear as sprites outside of battle (excluding Difloon), I used my Master Ball just so I could softreset until I obtained a Giratina viable for competitive battling.
I used a normal Pokeball. I was REALLY lucky I tell you. Especially considering the fact I caught it the first try. I was trying to be funny and I told my brother "Hey, Watch me catch it with a Pokeball." And click I caught him. My jaw dropped so far. ^_^ Lucky me.