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Caught Tornadus w/ a quick ball (after catching a Golbat w/Mean Look and bringing its health down to red), caught Cobalion, Terrakion, Virizion, and Volcarona w/ Ultra Balls and Quick Balls, used the Masetr Ball on Kyurem. However, in Volt White I still have my master ball. Caught Kyurem with an Ultra Ball.
I MIGHT use it on Metang in VW weird as that sounds. Metang have a horrible catch rate and I remember wasting a lot of time and ultra balls trying to get it in normal Black version. I still don't have one actually. I ended up killing it by accident.
I played Black, caught Reshiram with an ultra ball.
I traded my Pokémon to a friend, Reshiram holding the masterball, and restarted Black.
I caught Reshiram with a Pokéball on the first try. My friend traded back my Pokémon. I caught Kyurem with a dusk ball. I have two masterballs and nothing worth capturing with them so far.
I'm playing White. I think I'll try to catch Zekrom with a premier ball. I love those things almost as much as I love timer balls. <3 (•)
I am saving my Master Ball for when I encounter a shiny :D like a shiny Legendary that is. I don't see the point of using it on anything other than that.
After reading some posts I might save it because sometimes I forget to get pokeballs, and that would be my luck to encounter a shiny. So I might just save it.
I used one of my masterballs on Thundurus, another on Tornadus on Black anddd that leaves me with one masterball on White which was achieved by trading with 50 people and getting the second masterball.
I used it on Zekrom. I wanted to make sure I got one with at least adequate IVs and nature, and since I HAD to catch it, I didn't feel like wasting time for something inadequate. (Luckily I got Adamant 31 Attack IV on the second/third attempt.)
I have yet to use my Masterball. I usually don't anyway, since all the Pokémon within the game are easily obtainable to me. Though if there is ever a need for me to use it, is when I'd be glad I saved it. n_n;
I didn't use my Master Ball. I'll save it for now, but I already caught all the legendary Pokemon in Unova without the Master Ball (excluding the event ones).
I used my first Master Ball on Tornadus, cuz really, who enjoys wasting one Pokeball after another on someone who will just run away on the first turn. I got the second in-game Master Ball, but I'm gonna save it for a shiny.