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I don't have an iPod because apple sells them at outrageous prices in which you can buy a new video game console for. I'm broke, but the artist that appears on my MP3 player the most is Daft Punk
My PSP w/ 2GB stick is being used as a flash drive more than anything else right now, so it would be unfair for me to say IOSYS. Also, IOSYS is a doojin circle, not a single band or artist; so I'll say Rammstein since they were the most on my PSP when it did have a lot of music on it.
I don't have a iPod. Those area pretty expensive, so I got a Sony MP3 Walkman. And I think Rihanna appear most in my MP3 player. Her or Daft Punk, lol.
Bullet For My Valentine, VERY closely followed by Three Days Grace. If it weren't for two songs being on iTunes yet not my iPod (despite it being compatible and synced to it many times o_O) then it would be TDG.
Oh, geez. If I put my iPod on Shuffle, I'm sure Linkin Park would appear most, as I have all their songs on there, but if you mean what do I play the most, that'd have to be Panic at the Disco. XD; Probably my favorite band of all time.