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Again I go to the first episode.
Seen in the old school game openings, It requires two screenshots to explain it but the second one is my actual entry.
Day 4, my 2nd submission though, credited from Serebii again.
I couldn't seem to find a great screenshot but then again, I don't remember the TV fitting Brock's & Misty's entire faces into the screen at once here though, so its the best I could get. This was during Holy Matrimony with James & Growlithe..James was telling a story about his younger days with Growlithe & freezing to death by the church. Brock said "I can't believe James is gone!!!" & Misty, to the left of Ash, was getting upset to the fact that he was RIGHT IN FRONT OF THEM! haha. That moment right there was just straight up hilarious x)
I laugh pretty hard at this scene, especially at Ash's face when Pikachu yells at him. I replay this all the time and watch the episode just for this scene.
Screenshot taken by me.
(And yes it's under 500x500. I resized it to 500x281 exactly.
Misty is impressed with Brock, and decides to ensure he keeps his nose out of Officer Jenny and Nurse Joy's business... Source:https://pokecapture.livejournal.com/
In all reality, I actually ended up looking up the wrong episode for a certain scene, but the sheer absurdity and facial expressions of both Brock and Ash had me literally laughing out loud, so I figured that this picture would do just fine.