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I've only managed to do it once, and that was with a Luxray in Platinum. Made it all the way through the game with just that and two HM slaves. However, it eventually got canned by Cynthia's Garchomp, and wasn't able to get around it till I got more cannon fodder. :P
Well I did it with an Electabuzz in Silver in a Solo challenge but I'm not sure if you'd count that. I didn't beat the Elite Four on G/S/C as a kid, I couldn't get through Ice Path or whatever you call the cave between Mahogany and Blackthorn which is quite embarrassing.
I managed to get through the entire Johto Region/Pokémom League with just my Totodile/Croconaw/Feraligatr. It was both my powerhouse and HM slave. By the time I got to the League, I believe it was already close to 70. Haha.
Almost the same Moveset as myself. I gave it Surf, Ice Beam, Crunch, Strength. Of course, I had to have a few extras solely for Cut, Fly, Whirlpool and Waterfall.
Yeah. Most recently in Black 2 I trained up my Starmie to like level 70 and taught it Ice Beam, Thunderbolt, Hydro Pump, and Surf. That knocked out not only the E4 but also Iris all by itself!
Couple years ago, I did the Celebi Glitch to get Mewtwo (It's a good thing that Splash is the move needed), raised it to 100, and it ****s up everything that stands on its way.
I didn't know you were supposed to level up multiple Pokemon, so I defeated the E4+Lance in Crystal with just a level 64 Typhlosion (and my Lvl 24 Spinarak, in case Fire Dude (my Typhlosion) fainted, so I could Revive him.
When I was first into pokemon, I thought metronome was the best move of all time, so I made my togepi extremely overpowered without evolving it because, ew, wings. I pumped everything I had into it, it was poisoned? Holy sh*t get that pokemon a pecha berry asap! It was down by one hp? Use the hyper potion! Seriously, togepi is #3 on my top ten list of pokemon.
XD I was stupid as a kid so I trained Charizard to level 100 to challenge everything head on. I was stupid to have Fly, Blast Burn, Flamethrower and Ember I Blast Burned everything to death.