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well, i used route 201, 202 and orebough mine to ev train my cresselia and when it leveled up it got +35 in hp, +17 in def and +15 SP. Def, this is because finished ev training in 1 level. :)
My Luxray's been getting a consistent +6 in either Attack or Speed, but that's not much.
There's a screenshot on a Facebook group that has somebody's Gallade leveling to 96 and getting a +50 in Attack and +63 in Sp. Def. The poster also said that it was rare candied to 95 and EV trained from there.
you know what, i switch trained my hoppip to get the evs, but i didn't realize that it only get half as much with switch training, so i had to get another hoppip. :(