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Shinji! <3 Squeeee. . He's just not the run-of-the-mill trainer that you see in all of those awful fillers. He's the best!! And then I love Jun, he's cool, too.
May! shes the best girl in the whole anime!
Ash is cool, cuz hes like, the main character.
Paul. He is easy the best rival. except the old Gary. he was really good.
Though she hasn't been revealed in the anime (I don't think think.), based on the game, Marley has to be my favorite character.
=]
But out of who's been revealed, I'd have to say The Sensational Sisters. Although they are minor characters.
Croagunk. His relationship with Brock is priceless, and pretty much the only thing keeping Brock interesting. Also, he made me actually like Brock's flirting gag, what with the wanton trainer abuse being added.
Paul. He's Ash's best rival, as he's the exact opposite of Ash, from how he treats his Pokemon to his general world view. Does anyone think it's chance that Paul lives in Veilstone, maybe he and Cyrus are related?