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The last Pokemon that I caught was an Excadrill in the Giant Chasm (took me 1 Dusk Ball). I've been wanting to train one for a while now, but just never got around to catching one.
I tried to catch it using all of my Ultra Balls, Timer Balls and Dusk Balls (I encountered it at night), but she keeps escaping. However, I used a single Great Ball and finally the ball locks. :\ I can guess that's why it's called the Great Ball.
A Ralts in a Cherish Ball which was attached to my Platinum Arceus, the Ralts ended up as a really useful team member till the 7th gym when it fainted battling Drayden, R.I.P Harmonia (I was doing a nuzlocke).
The last Pokémon I caught was a Hustle Nidoran (male) from the Route 2 Hidden Grotto after so many tries of making one appear. It's currently a Nidoking.
I just went and caught a male riolu for breeding purposes. Before that it was my shiny absol. :3 I've been done with the game and national dex for quite a while so I haven't been catching many pokemon..
Last Pokemon I caught was a Lv. 19 Sigilyph with an ultra ball.
I planned on training him up to help me in my mission to defeat the Elite 4. Halfway through training him, I thought "I'll take on the Elite 4 again" (Having lost a few times already) and what do you know I ended up beating them, didn't even need Sigilyph
I'm still going to train him up though, pretty strong Psychic type. :)