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All of those are good pokes, but they serve different functions. As much as I love Blaziken and Volcarona, Easy Bake Oven Rotom-H is probably the better fit for your team, to give you something that is more specially defensive and can spread status. You already have 4 offensive pokes, so let's round it out with a more defensive one. The set I had in mind was:
-Heat Rotom w/Leftovers
Nature: Calm
Ability: Levitate
EVs: 248 HP, 8 Defense, 252 Sp.Defense
Moves: Overheat, Volt-Switch/Thunderbolt, Thunder Wave, Will-o-Wisp
Moltres is a Pokemon I've never cared much for, but I guess its not bad. You could use it if you really want to. And yes, if you save before battling it (save BEFORE you enter the cave) you can soft reset to get the IVs and nature you want. If you like soft reseting a lot. But it'd probably still be better too use other fire types in Wifi battles.
Oh, and Rotom-H pairs fairly well with Skarmory, since Rotom resists Fire and Electric, which Skarm is weak to, and if you use the set I posted, it takes those special attacks that physically defensive Skarmory isn't too fond of pretty well.
-Heat Rotom w/Leftovers
Nature: Calm
Ability: Levitate
EVs: 248 HP, 8 Defense, 252 Sp.Defense
Moves: Overheat, Volt-Switch/Thunderbolt, Thunder Wave, Will-o-Wisp
Moltres is a Pokemon I've never cared much for, but I guess its not bad. You could use it if you really want to. And yes, if you save before battling it (save BEFORE you enter the cave) you can soft reset to get the IVs and nature you want. If you like soft reseting a lot. But it'd probably still be better too use other fire types in Wifi battles.
Oh, and Rotom-H pairs fairly well with Skarmory, since Rotom resists Fire and Electric, which Skarm is weak to, and if you use the set I posted, it takes those special attacks that physically defensive Skarmory isn't too fond of pretty well.