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I used dusk balls, and I carried 70 of them. I went through my entire stock, reset the game and tried again. I ended up using 50 of them the second time before I caught it.
Timer ball. I went in with 30 ultra balls, 50 dusk balls, like a hundred something pokeballs, master ball, and 15 timer balls. I depleted all my ultra balls and 20 dusk balls before i was like "ok this has been going on so long..." 1st timer ball. I have to say i had a harder time catching Azelf than any other legendary.
I used a premiere ball for lol. I got 10 pokeballs and sold them and then another 10 and went on until I had 50 premiere balls. Caught 1st try. (it had full HP and I still caught him!!!)
i catch mine in a timer ball. wanted it in a dusk ball. i had like 12 timer balls and 10 or 12 dusk balls and just went back and fourth with the two balls and got it in a timer ball. o well i was to lazy to reset the game to try it again and catch it in the dusk ball.