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First catch was an Eevee. Spent ages walking around trying to track down a damn Ratatta and just as I'm about to give up, nope, Eevee showed up at random... wasn't even listed as nearby when I found it which was rather odd.
I got a Clefairy also. My friend was looking for a Pikachu but I got it before him. Although I would've love more if I had caught a Pidgey or Pidgeotto as my first.
After picking my starter my first pokemon was a Pidgey. I had just come out of the screen and there it was waiting for me :) I walked all of a few steps away and then a Bulbasaur popped up to. Got ready for my morning run and went out and ended up catching 3 Eevee's in a row. Apparently my neighborhood is a hotspot for Eevees :)
An Eevee! It wasn't the first Pokemon I encountered since I let the Zubat in my backyard get away, but the stationary Eevee I met after dinner was much easier to catch, lol.