If we're talking about a make-believe PC, I'd love to rule a Funny section! What would be more fun than going to your section to have a laugh while taking care of forum business?!
But seriously, I've moderated OC before, and while it wasn't very different from being a regular member, I still enjoyed it because I got to talk to my friends a lot about their day and other stuff. However, if given the chance, I wouldn't want to moderate anything- life is just too busy to take that sort of responsibility, and I actually find it would be a bit boring for me nowadays.