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I'm not really a fan of lucario, so I didn't end up using it. I had a team of 6 by that point anyways, and I didn't want to box anyone for lucario's sake. All that aside, being handed a fully evolved pokemon capable of mega evolving just like that seems a bit too....easy, if that makes any sense. I mean, make me work a little bit more for the overpoweredness that is mega lucario.
I used it on my first full Y playthrough, it was the only mega evo that I used throughout as I ditched all the starters (I went on a bit of a nostalgiarun).
I used mine in my B Team because I did want to use it but didn't really have a place for it. And by B Team I mean the ones that sweep the Chateau over and over so I can evolve 'mon for the dex. -v- He always does pretty well there, considering he's got an advantage over a fair few leaders/e4 members and the Furisode girls.