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Yes, but usually only as a last resort. I try not to use potions that much, but if it is my last mon on field and it's almost fainting, I'm gonna break that mold.
Usually just in the E4! In most other battles I've no need to use items, since I find them easy enough. Occasionally gym leaders/trials too, but not very often.
If I need to...which honestly, I rarely do. I'm the kind of person who likes to grind, so battles for me usually consist of one-shotting my opponent's Pokemon. When battling in the wild I usually just go to a Pokemon Center.