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I usually have alot of Ultra balls. They have the highest catch ratio, besides the Master ball, and I usually don't like waiting long to catch the pokemon I want, so I use Ultra balls.
Great balls always seem to work better than Ultra balls for me. I managed to catch the ledgendary birds with Great balls, but they wouldn't even stay in them with Ultras.
Ultra balls everytime. But if I have any poke balls on me i use them first cos they look cooler. Anyone who says that ultra balls cost too much is stupid. Really its too easy to get money, so cost should NEVER be an issue for anybody.