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I know that in the competitive metagame, something like Sludge Bomb or Toxic would be better overall, but Poison Fang is like both wrapped into one. :D
What an interesting question that I'm really not sure of. :/
I feel like I end up teaching almost all of my teams Earthquake. So perhaps that's it? Earthquake as my signature move sounds really boring though. I wish I had something a bit more -flashy-
Razorleaf for my Bulbasaur, Confuse Ray from Haunter, and I always taught Blizzard to my Dragonair. Always the moves I use to try and finish off a dramatic, high-tension match.
My Ponyta (soon to be Rapidash) loves to finish off matches with a hefty Fire Blast. Otherwise my Grotle makes good use of Grass Knot and my Pichu loves to fry Pokemon with Thunder :D.
Dragon Dance, If any DDancer gets it twice, then the battle is basicly finished, even I only got once, they can cause huge damage to the opposing team if done right.