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The last Pokemon I caught was a shiny Mareep I was looking for. It was only level 5 so it only took one ultra ball. Already evolved it into Ampharos, the best pokemon of all.
About 3 days ago, I caught Riolu in Floccesy Ranch - before 1st badge. Before I never encountered it in the wild, so I was just raising the levels of my Patrat and Oshawott for battle against Cheren. Faced Riolu 3 times, so I had to catch it the first time, took me 2 Pokeballs to catch.
Last Pokemon I caught was the Volcarona in Relic Castle when it was at level 35. Wasn't sure if it come back if I defeated it so I saved and reset a few times until I caught it with an Ultra Ball.
Last thing I caught - yesterday - was a Sheer Force Kingler (male) in the grotto out on the island at the end of Route 18. I was really hoping for a Dragonite, but at least it was an actual pokemon, instead of a poke ball or a mulch, so there's that.
Azelf, Took about 30 ultra balls. I'm not kidding. Kinda sucks when you can't hurt it or it dies instantly.
The first time it took 5-6 ultra balls... And then the game crashed... FFFFUUUUU!!!! (Me and my luck)
The second time I killed it by accent.
And the third it took 30+ Ultra Balls.
I swear, whats its catch rate, .5?????
A Ralts in a Cherish Ball which was attached to my Platinum Arceus, the Ralts ended up as a really useful team member till the 7th gym when it fainted battling Drayden, R.I.P Harmonia (I was doing a nuzlocke).
I don't know if you have to have finished the game to post here cause I haven't. But the last thing I caught was an Evee in castelia open lot with something like 5 great balls and 5 or 6 poke balls.