Sun
When the sun goes down...
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- Seen Jan 20, 2017
As far as non-legendaries go, I've always had trouble with Skarmory and Onix. Both have surprisingly low catch rates for the point in the game you first encounter them (especially Onix, which usually appears right after you pick up your first Great Ball but before you can buy them in shops). In almost every game I have used up my entire stock of Pokéballs the first time I try to catch one or the other.
Red Gyarados was also very tough for me, and I didnt even catch him. I also found Togekiss to be very hard to catch in my randomized nuzlocke. No matter how low it got and how asleep it was, it would not get caught. Eventually, I was forced to just faint it.
I second that Skarmory, Whether we're talking about SoulSilver or RSE it's a hell to catch them.
Both Togekiss and Skarmory have lower catch rate than the Rayquaza from Omega Ruby and Alpha Sapphire, with Skarmory as the lowest among the three mentioned Pokémon.