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I only used dusk balls until i got so pissed off about how many I wasted that I just threw one of my 10 masterballs. So much work wasted for that one catch that turned out to be a crappy statted Giratina, I was kinda mad cuz I had to reset to like the right after beating the elite four.
I'm old fashioned, and typically refuse to use anything buy a pokeball. It took me twenty minutes, and over 25 pokeballs, but I finally caught him/her/it!
I used the Master Ball on my second attempt. Got pretty annoyed that he destroyed my whole team the first time round. I thought I'd regret it later, but after catching Dialga with 1 Ultra Ball and Palkia with my 4th, I'm pretty sure I'll be fine.