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Oh geez I don't actually remember...of course not counting main game and Delta Episode...I believe I went after Lugia first. It is my favorite Legendary after all.
I think I stumbled across the Lake Guardians first, not actually knowing you could find all the legendaries, so I was quite surprised. I caught it and moved on to the next, but I never finished getting them all.
In both OR and AS, I went for the G/S mascots first (Ho-Oh and Lugia) because of their low total PP in their moves. I wanted them out of the way first.
Ho-Oh! Only because I found it on accident while exploring the ship. As for the others, I'm waiting until I have the patience to soft reset them. I want something good, like maybe a shiny :3 Though unsure when I'd ever have the patience for that.
I first noticed the little light above Terrakion, Cobalion and Virizion. I think Virizion was my first because of whatever day I was catching on. Well, to be honest I think I got Groudon first because the fact it was OR I was playing.
I went for the lake guardians and ended up with Mesprit shes so cute so i was quite happy!
Afterwords i went for Reshiram which wasnt as challenging as Mesprit surprisingly.
I was going after Mesprit first because I got some light notice on one of the caves, so I decided to go there. After catching it, I also found Virizion on the same day as well.
I also think I ran into Azelf on accident while trying out the soaring feature. I battled it, but soft reset afterwards. The first legendary I captured was Zekrom because its shiny form is now available.